Tungsten Distribution in Soil and Rice in the Vicinity of the World's Largest and Longest-Operating Tungsten Mine in China
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{"title"=>"Tungsten distribution in soil and rice in the vicinity of the World's largest and longest-operating tungsten mine in China", "type"=>"journal", "authors"=>[{"first_name"=>"Chunye", "last_name"=>"Lin", "scopus_author_id"=>"8703465200"}, {"first_name"=>"Ruiping", "last_name"=>"Li", "scopus_author_id"=>"55653467000"}, {"first_name"=>"Hongguang", "last_name"=>"Cheng", "scopus_author_id"=>"7404286048"}, {"first_name"=>"Jing", "last_name"=>"Wang", "scopus_author_id"=>"56115534300"}, {"first_name"=>"Xiao", "last_name"=>"Shao", "scopus_author_id"=>"55570738400"}], "year"=>2014, "source"=>"PLoS ONE", "identifiers"=>{"sgr"=>"84898662188", "pmid"=>"24642612", "scopus"=>"2-s2.0-84898662188", "pui"=>"372837956", "issn"=>"19326203", "doi"=>"10.1371/journal.pone.0091981"}, "id"=>"2a23fa85-9b66-3b4d-9adc-49ad3883921e", "abstract"=>"Tungstate adsorption in soils is critical to understand tungstate mobility and bioavailability, but study of this is lacking. The objectives of this study are to investigate the kinetics and isotherms of tungstate adsorption onto oxisol samples in the vicinity of the world's largest and longest-operating tungsten mine in China. In addition, the effects of pH, ionic strength, and phosphate anion on tungstate adsorption onto the soil were studied. Results show that the tungstate adsorption kinetics is fitted best by a pseudo-second order model. Micropore (intraparticle) diffusion and ultramicropore (within clays) diffusion are generally the adsorption- limiting mechanisms. Tungstate adsorption isotherms are fitted well by both Langmuir and Freundlich models. The maximal adsorption capacity of the oxisol sample is 10.67 mmol kg?1, while the distribution coefficient is 12.60 (mmol kg?1) (mol L?1)?1/n. Tungstate adsorption decreased from 96.1% to 90.2% with the pH increase from 4.93 to 5.23, while it increased from 90.1% to 95.5% with the increase of ionic strength from 0.01 M to 0.1 M NaCl. With the increase of phosphate concentration from 0.008 mM to 0.215 mM, tungstate adsorption slightly decreased from 2.32 mmol kg?1 to 1.97 mmol kg?1. These results demonstrate that tungstate might be adsorbed onto the tungstate-specific adsorption sites of the soil minerals mainly via inner-sphere complexation. Despite the soil containing a high tungsten content (e.g. 21.9 mg kg?1), it still has a high tungstate adsorption capacity.", "link"=>"http://www.mendeley.com/research/tungsten-distribution-soil-rice-vicinity-worlds-largest-longestoperating-tungsten-mine-china", "reader_count"=>13, "reader_count_by_academic_status"=>{"Researcher"=>1, "Student > Doctoral Student"=>2, "Student > Ph. D. Student"=>1, "Student > Master"=>3, "Other"=>1, "Student > Bachelor"=>2, "Professor"=>2, "Professor > Associate Professor"=>1}, "reader_count_by_user_role"=>{"Researcher"=>1, "Student > Doctoral Student"=>2, "Student > Ph. D. Student"=>1, "Student > Master"=>3, "Other"=>1, "Student > Bachelor"=>2, "Professor"=>2, "Professor > Associate Professor"=>1}, "reader_count_by_subject_area"=>{"Engineering"=>2, "Environmental Science"=>3, "Medicine and Dentistry"=>1, "Agricultural and Biological Sciences"=>3, "Chemistry"=>2, "Psychology"=>1, "Social Sciences"=>1}, "reader_count_by_subdiscipline"=>{"Engineering"=>{"Engineering"=>2}, "Medicine and Dentistry"=>{"Medicine and Dentistry"=>1}, "Chemistry"=>{"Chemistry"=>2}, "Social Sciences"=>{"Social Sciences"=>1}, "Psychology"=>{"Psychology"=>1}, "Agricultural and Biological Sciences"=>{"Agricultural and Biological Sciences"=>3}, "Environmental Science"=>{"Environmental Science"=>3}}, "reader_count_by_country"=>{"Colombia"=>1}, "group_count"=>1}

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Figshare

  • {"files"=>["https://ndownloader.figshare.com/files/1425038"], "description"=>"<p>Schematic graph of W mine locations and soil sampling areas.</p>", "links"=>[], "tags"=>["agriculture", "crops", "Cereal crops", "rice", "toxicology", "Toxic agents", "toxins", "Heavy metals", "geochemistry", "Biogeochemistry", "chemistry", "Environmental chemistry", "pollutants", "Soil chemistry", "Model organisms", "Plant and algal models", "graph", "locations", "sampling"], "article_id"=>965778, "categories"=>["Biological Sciences", "Ecology"], "users"=>["Chunye Lin", "Ruiping Li", "Hongguang Cheng", "Jing Wang", "Xiao Shao"], "doi"=>["https://dx.doi.org/10.1371/journal.pone.0091981.g001"], "stats"=>{"downloads"=>0, "page_views"=>0, "likes"=>0}, "figshare_url"=>"https://figshare.com/articles/_Schematic_graph_of_W_mine_locations_and_soil_sampling_areas_/965778", "title"=>"Schematic graph of W mine locations and soil sampling areas.", "pos_in_sequence"=>0, "defined_type"=>1, "published_date"=>"2014-03-18 03:42:13"}
  • {"files"=>["https://ndownloader.figshare.com/files/1425039"], "description"=>"<p>Proportion of W in each chemical forms in the soil.</p>", "links"=>[], "tags"=>["agriculture", "crops", "Cereal crops", "rice", "toxicology", "Toxic agents", "toxins", "Heavy metals", "geochemistry", "Biogeochemistry", "chemistry", "Environmental chemistry", "pollutants", "Soil chemistry", "Model organisms", "Plant and algal models", "forms"], "article_id"=>965779, "categories"=>["Biological Sciences", "Ecology"], "users"=>["Chunye Lin", "Ruiping Li", "Hongguang Cheng", "Jing Wang", "Xiao Shao"], "doi"=>["https://dx.doi.org/10.1371/journal.pone.0091981.t002"], "stats"=>{"downloads"=>0, "page_views"=>0, "likes"=>0}, "figshare_url"=>"https://figshare.com/articles/_Proportion_of_W_in_each_chemical_forms_in_the_soil_/965779", "title"=>"Proportion of W in each chemical forms in the soil.", "pos_in_sequence"=>0, "defined_type"=>3, "published_date"=>"2014-03-18 03:42:13"}
  • {"files"=>["https://ndownloader.figshare.com/files/1425041"], "description"=>"<p>W contents in rice root, stem, leaf, and grain and its enrichment factor in them.</p>", "links"=>[], "tags"=>["agriculture", "crops", "Cereal crops", "rice", "toxicology", "Toxic agents", "toxins", "Heavy metals", "geochemistry", "Biogeochemistry", "chemistry", "Environmental chemistry", "pollutants", "Soil chemistry", "Model organisms", "Plant and algal models", "contents", "enrichment"], "article_id"=>965781, "categories"=>["Biological Sciences", "Ecology"], "users"=>["Chunye Lin", "Ruiping Li", "Hongguang Cheng", "Jing Wang", "Xiao Shao"], "doi"=>["https://dx.doi.org/10.1371/journal.pone.0091981.t003"], "stats"=>{"downloads"=>0, "page_views"=>0, "likes"=>0}, "figshare_url"=>"https://figshare.com/articles/_W_contents_in_rice_root_stem_leaf_and_grain_and_its_enrichment_factor_in_them_/965781", "title"=>"W contents in rice root, stem, leaf, and grain and its enrichment factor in them.", "pos_in_sequence"=>0, "defined_type"=>3, "published_date"=>"2014-03-18 03:42:13"}
  • {"files"=>["https://ndownloader.figshare.com/files/1425042"], "description"=>"<p>1: Data are cited from reference <a href=\"http://www.plosone.org/article/info:doi/10.1371/journal.pone.0091981#pone.0091981-Wei1\" target=\"_blank\">[34]</a>.</p><p>2: Data are cited from reference <a href=\"http://www.plosone.org/article/info:doi/10.1371/journal.pone.0091981#pone.0091981-Bowen2\" target=\"_blank\">[35]</a>.</p>", "links"=>[], "tags"=>["agriculture", "crops", "Cereal crops", "rice", "toxicology", "Toxic agents", "toxins", "Heavy metals", "geochemistry", "Biogeochemistry", "chemistry", "Environmental chemistry", "pollutants", "Soil chemistry", "Model organisms", "Plant and algal models", "matrix", "elements"], "article_id"=>965782, "categories"=>["Biological Sciences", "Ecology"], "users"=>["Chunye Lin", "Ruiping Li", "Hongguang Cheng", "Jing Wang", "Xiao Shao"], "doi"=>["https://dx.doi.org/10.1371/journal.pone.0091981.t001"], "stats"=>{"downloads"=>0, "page_views"=>0, "likes"=>0}, "figshare_url"=>"https://figshare.com/articles/_Contents_of_mineral_matrix_elements_and_W_in_the_soil_/965782", "title"=>"Contents of mineral matrix elements and W in the soil.", "pos_in_sequence"=>0, "defined_type"=>3, "published_date"=>"2014-03-18 03:42:13"}
  • {"files"=>["https://ndownloader.figshare.com/files/1425043"], "description"=>"<p>*mg W kg<sup>−1</sup> ash weight, R<sup>2</sup>: correlation coefficient, n: number of samples, Ref.: reference.</p>", "links"=>[], "tags"=>["agriculture", "crops", "Cereal crops", "rice", "toxicology", "Toxic agents", "toxins", "Heavy metals", "geochemistry", "Biogeochemistry", "chemistry", "Environmental chemistry", "pollutants", "Soil chemistry", "Model organisms", "Plant and algal models", "contents", "plants", "mg", "soils", "mining", "investigations", "experiments", "w-spiked"], "article_id"=>965783, "categories"=>["Biological Sciences", "Ecology"], "users"=>["Chunye Lin", "Ruiping Li", "Hongguang Cheng", "Jing Wang", "Xiao Shao"], "doi"=>["https://dx.doi.org/10.1371/journal.pone.0091981.t004"], "stats"=>{"downloads"=>0, "page_views"=>0, "likes"=>0}, "figshare_url"=>"https://figshare.com/articles/_Relationship_between_the_contents_of_W_in_plants_Y_mg_W_kg_8722_1_dry_weight_and_in_soils_X_mg_kg_8722_1_for_W_mining_field_investigations_and_pot_experiments_with_W_spiked_soils_/965783", "title"=>"Relationship between the contents of W in plants (Y, mg W kg<sup>−1</sup> dry weight) and in soils (X, mg kg<sup>−1</sup>) for W mining field investigations and pot experiments with W-spiked soils.", "pos_in_sequence"=>0, "defined_type"=>3, "published_date"=>"2014-03-18 03:42:13"}
  • {"files"=>["https://ndownloader.figshare.com/files/1425044"], "description"=>"<p>Note: R-W: root W content, S-W: stem W content, L-W: leaf W content, G-W: grain W content. * Significant at <i>p = 0.01</i> level.</p>", "links"=>[], "tags"=>["agriculture", "crops", "Cereal crops", "rice", "toxicology", "Toxic agents", "toxins", "Heavy metals", "geochemistry", "Biogeochemistry", "chemistry", "Environmental chemistry", "pollutants", "Soil chemistry", "Model organisms", "Plant and algal models", "matrix", "forms", "contents"], "article_id"=>965784, "categories"=>["Biological Sciences", "Ecology"], "users"=>["Chunye Lin", "Ruiping Li", "Hongguang Cheng", "Jing Wang", "Xiao Shao"], "doi"=>["https://dx.doi.org/10.1371/journal.pone.0091981.t005"], "stats"=>{"downloads"=>0, "page_views"=>0, "likes"=>0}, "figshare_url"=>"https://figshare.com/articles/_Correlation_matrix_among_mineral_matrix_element_W_content_and_chemical_forms_in_soil_and_W_contents_in_rice_root_stem_leaf_and_grain_/965784", "title"=>"Correlation matrix among mineral matrix element, W content and chemical forms in soil, and W contents in rice root, stem, leaf, and grain.", "pos_in_sequence"=>0, "defined_type"=>3, "published_date"=>"2014-03-18 03:42:13"}

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Relative Metric

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