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{"title"=>"Supported palladium nanoparticles synthesized by living plants as a catalyst for Suzuki-Miyaura reactions", "type"=>"journal", "authors"=>[{"first_name"=>"Helen L.", "last_name"=>"Parker", "scopus_author_id"=>"53463938100"}, {"first_name"=>"Elizabeth L.", "last_name"=>"Rylott", "scopus_author_id"=>"8721405800"}, {"first_name"=>"Andrew J.", "last_name"=>"Hunt", "scopus_author_id"=>"35563909000"}, {"first_name"=>"Jennifer R.", "last_name"=>"Dodson", "scopus_author_id"=>"36959587600"}, {"first_name"=>"Andrew F.", "last_name"=>"Taylor", "scopus_author_id"=>"56144967900"}, {"first_name"=>"Neil C.", "last_name"=>"Bruce", "scopus_author_id"=>"7102846571"}, {"first_name"=>"James H.", "last_name"=>"Clark", "scopus_author_id"=>"7407828513"}], "year"=>2014, "source"=>"PLoS ONE", "identifiers"=>{"pmid"=>"24489869", "sgr"=>"84900324515", "doi"=>"10.1371/journal.pone.0087192", "scopus"=>"2-s2.0-84900324515", "pui"=>"373059931", "isbn"=>"10.1371/journal.pone.0087192", "issn"=>"19326203"}, "id"=>"33af9af0-ae72-3fb5-9ee3-a119e393bee4", "abstract"=>"The metal accumulating ability of plants has previously been used to capture metal contaminants from the environment; however, the full potential of this process is yet to be realized. Herein, the first use of living plants to recover palladium and produce catalytically active palladium nanoparticles is reported. This process eliminates the necessity for nanoparticle extraction from the plant and reduces the number of production steps compared to traditional catalyst palladium on carbon. These heterogeneous plant catalysts have demonstrated high catalytic activity in Suzuki coupling reactions between phenylboronic acid and a range of aryl halides containing iodo-, bromo- and chloro- moieties.", "link"=>"http://www.mendeley.com/research/supported-palladium-nanoparticles-synthesized-living-plants-catalyst-suzukimiyaura-reactions", "reader_count"=>35, "reader_count_by_academic_status"=>{"Professor > Associate Professor"=>1, "Researcher"=>8, "Student > Doctoral Student"=>2, "Student > Ph. D. Student"=>13, "Student > Postgraduate"=>3, "Student > Master"=>5, "Student > Bachelor"=>2, "Unspecified"=>1}, "reader_count_by_user_role"=>{"Professor > Associate Professor"=>1, "Researcher"=>8, "Student > Doctoral Student"=>2, "Student > Ph. D. Student"=>13, "Student > Postgraduate"=>3, "Student > Master"=>5, "Student > Bachelor"=>2, "Unspecified"=>1}, "reader_count_by_subject_area"=>{"Unspecified"=>3, "Engineering"=>2, "Environmental Science"=>7, "Materials Science"=>2, "Agricultural and Biological Sciences"=>8, "Medicine and Dentistry"=>1, "Pharmacology, Toxicology and Pharmaceutical Science"=>1, "Chemistry"=>11}, "reader_count_by_subdiscipline"=>{"Engineering"=>{"Engineering"=>2}, "Materials Science"=>{"Materials Science"=>2}, "Medicine and Dentistry"=>{"Medicine and Dentistry"=>1}, "Chemistry"=>{"Chemistry"=>11}, "Agricultural and Biological Sciences"=>{"Agricultural and Biological Sciences"=>8}, "Unspecified"=>{"Unspecified"=>3}, "Environmental Science"=>{"Environmental Science"=>7}, "Pharmacology, Toxicology and Pharmaceutical Science"=>{"Pharmacology, Toxicology and Pharmaceutical Science"=>1}}, "reader_count_by_country"=>{"Mexico"=>1, "India"=>1}, "group_count"=>2}

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• http://doi.org/10.1039/C5CS00133A
• http://doi.org/10.1039/C4GC02483D
• http://doi.org/10.1016/j.scitotenv.2020.140536
• http://doi.org/10.3389/fchem.2020.00799
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• http://doi.org/10.1039/C9GC02291K
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• http://doi.org/10.1039/C5SC03116H
• http://doi.org/10.1016/j.apcatb.2016.10.074
• http://doi.org/10.1016/j.pmatsci.2019.05.004
• http://doi.org/10.1007/s41204-020-00095-9
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• http://doi.org/10.1002/cssc.202002532
• http://doi.org/10.1590/0370-44672019730038
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• http://doi.org/10.1039/C8GC03015D
• http://doi.org/10.1021/acs.est.6b04821
• http://doi.org/10.3389/fchem.2020.00140

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• {"referral"=>"http://www.rsc.org/chemistryworld/2014/02/plants-bear-palladium-catalyst-fruit-suzuki", "language"=>"English", "title"=>"Plants bear palladium catalyst fruit | Chemistry World", "type"=>"Blog", "publication"=>"", "published_on"=>"", "link_state"=>""}

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• {"id"=>"431027392534962176", "text"=>"Check out our two new open access Phytocat papers available online - http://t.co/RsLLJM63mk and http://t.co/shri47JZ78", "created_at"=>"2014-02-05T11:31:53Z", "user"=>"GreenChemYork", "user_name"=>"Green Chemistry York", "user_profile_image"=>"http://pbs.twimg.com/profile_images/378800000010107147/ae2c45e0f2d88cd886c560ecf5efff06_normal.jpeg"}
• {"id"=>"431284177153953792", "text"=>"Products from Cambridge-based @AgarScientific used in this research: Spurrs resin + 400 mesh thin-bar Athene grids http://t.co/6qFCHRPI7M", "created_at"=>"2014-02-06T04:32:15Z", "user"=>"LabScholars", "user_name"=>"CambridgeLabScholars", "user_profile_image"=>"http://pbs.twimg.com/profile_images/378800000867171668/_mXLIQtK_normal.png"}
• {"id"=>"431322088046358528", "text"=>"RT @LabScholars: Products from Cambridge-based @AgarScientific used in this research: Spurrs resin + 400 mesh thin-bar Athene grids http://…", "created_at"=>"2014-02-06T07:02:54Z", "user"=>"AgarScientific", "user_name"=>"AgarScientific", "user_profile_image"=>"http://pbs.twimg.com/profile_images/3639218125/6df637d4b93f0edec633af9a2b1ebb24_normal.png"}

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• {"files"=>["https://ndownloader.figshare.com/files/1366577"], "description"=>"<p>Suzuki-Miyaura C-C coupling reaction of arylhalide with phenylboronic acid.</p>", "links"=>[], "tags"=>["Plant science", "plants", "Vascular plants", "Chemical reactions", "catalysis", "biocatalysis", "Heterogeneous catalysts", "synthesis", "Environmental chemistry", "pollutants", "Heavy metals", "organic chemistry", "Organic synthesis", "Synthetic chemistry", "biomaterials", "catalysts", "nanotechnology", "Bionanotechnology", "c-c", "coupling", "arylhalide", "phenylboronic"], "article_id"=>918148, "categories"=>["Biological Sciences", "Medicine", "Chemistry"], "users"=>["Helen L. Parker", "Elizabeth L. Rylott", "Andrew J. Hunt", "Jennifer R. Dodson", "Andrew F. Taylor", "Neil C. Bruce", "James H. Clark"], "doi"=>"https://dx.doi.org/10.1371/journal.pone.0087192.g003", "stats"=>{"downloads"=>1, "page_views"=>25, "likes"=>0}, "figshare_url"=>"https://figshare.com/articles/_Suzuki_Miyaura_C_C_coupling_reaction_of_arylhalide_with_phenylboronic_acid_/918148", "title"=>"Suzuki-Miyaura C-C coupling reaction of arylhalide with phenylboronic acid.", "pos_in_sequence"=>0, "defined_type"=>1, "published_date"=>"2014-01-29 03:58:56"}
• {"files"=>["https://ndownloader.figshare.com/files/1366578"], "description"=>"<p>(B) Distribution of PdNP sizes in the plant catalysts.</p>", "links"=>[], "tags"=>["Plant science", "plants", "Vascular plants", "Chemical reactions", "catalysis", "biocatalysis", "Heterogeneous catalysts", "synthesis", "Environmental chemistry", "pollutants", "Heavy metals", "organic chemistry", "Organic synthesis", "Synthetic chemistry", "biomaterials", "catalysts", "nanotechnology", "Bionanotechnology", "tem", "pdnps", "pd-p-300"], "article_id"=>918149, "categories"=>["Biological Sciences", "Medicine", "Chemistry"], "users"=>["Helen L. Parker", "Elizabeth L. Rylott", "Andrew J. Hunt", "Jennifer R. Dodson", "Andrew F. Taylor", "Neil C. Bruce", "James H. Clark"], "doi"=>"https://dx.doi.org/10.1371/journal.pone.0087192.g004", "stats"=>{"downloads"=>1, "page_views"=>10, "likes"=>0}, "figshare_url"=>"https://figshare.com/articles/_A_TEM_showing_PdNPs_in_Pd_P_300_and_Pd_P_800_/918149", "title"=>"(A) TEM showing PdNPs in Pd-P-300 and Pd-P-800.", "pos_in_sequence"=>0, "defined_type"=>1, "published_date"=>"2014-01-29 03:58:56"}
• {"files"=>["https://ndownloader.figshare.com/files/1366579"], "description"=>"[a]<p><i>Reaction conditions:</i> aryl halide (0.6 mmol), phenylboronic acid (0.7 mmol), TBAB (1 mmol), Na₂CO₃ (2 mmol), Pd-P-300 (12 mol % Pd) in EtOH:H₂O (2 ml:1 ml), NMR characterisation of products available in supporting information.</p>[b]<p>Isolated yields after column chromatography with <i>n</i>-pentane.</p>[c]<p>Isolated yield for Palladium on Carbon 10%.</p>[d]<p>Isolated yield for palladium acetate.</p>", "links"=>[], "tags"=>["Plant science", "plants", "Vascular plants", "Chemical reactions", "catalysis", "biocatalysis", "Heterogeneous catalysts", "synthesis", "Environmental chemistry", "pollutants", "Heavy metals", "organic chemistry", "Organic synthesis", "Synthetic chemistry", "biomaterials", "catalysts", "nanotechnology", "Bionanotechnology", "coupling", "aryl", "halides", "phenylboronic", "pd-p-300"], "article_id"=>918150, "categories"=>["Biological Sciences", "Medicine", "Chemistry"], "users"=>["Helen L. Parker", "Elizabeth L. Rylott", "Andrew J. Hunt", "Jennifer R. Dodson", "Andrew F. Taylor", "Neil C. Bruce", "James H. Clark"], "doi"=>"https://dx.doi.org/10.1371/journal.pone.0087192.t001", "stats"=>{"downloads"=>5, "page_views"=>19, "likes"=>0}, "figshare_url"=>"https://figshare.com/articles/_Suzuki_Miyaura_coupling_of_aryl_halides_with_phenylboronic_acid_under_Pd_P_300_catalysis_a_/918150", "title"=>"Suzuki-Miyaura coupling of aryl halides with phenylboronic acid under Pd-P-300 catalysis.^[a]", "pos_in_sequence"=>0, "defined_type"=>3, "published_date"=>"2014-01-29 03:58:56"}
• {"files"=>["https://ndownloader.figshare.com/files/1366608", "https://ndownloader.figshare.com/files/1366609", "https://ndownloader.figshare.com/files/1366610", "https://ndownloader.figshare.com/files/1366611", "https://ndownloader.figshare.com/files/1366612", "https://ndownloader.figshare.com/files/1366613", "https://ndownloader.figshare.com/files/1366614", "https://ndownloader.figshare.com/files/1366615", "https://ndownloader.figshare.com/files/1366616", "https://ndownloader.figshare.com/files/1366617", "https://ndownloader.figshare.com/files/1366618", "https://ndownloader.figshare.com/files/1366619", "https://ndownloader.figshare.com/files/1366620", "https://ndownloader.figshare.com/files/1366621"], "description"=>"<div><p>The metal accumulating ability of plants has previously been used to capture metal contaminants from the environment; however, the full potential of this process is yet to be realized. Herein, the first use of living plants to recover palladium and produce catalytically active palladium nanoparticles is reported. This process eliminates the necessity for nanoparticle extraction from the plant and reduces the number of production steps compared to traditional catalyst palladium on carbon. These heterogeneous plant catalysts have demonstrated high catalytic activity in Suzuki coupling reactions between phenylboronic acid and a range of aryl halides containing iodo-, bromo- and chloro- moieties.</p></div>", "links"=>[], "tags"=>["Plant science", "plants", "Vascular plants", "Chemical reactions", "catalysis", "biocatalysis", "Heterogeneous catalysts", "synthesis", "Environmental chemistry", "pollutants", "Heavy metals", "organic chemistry", "Organic synthesis", "Synthetic chemistry", "biomaterials", "catalysts", "nanotechnology", "Bionanotechnology", "palladium", "nanoparticles", "synthesized", "catalyst", "suzuki-miyaura"], "article_id"=>918174, "categories"=>["Biological Sciences", "Medicine", "Chemistry"], "users"=>["Helen L. Parker", "Elizabeth L. Rylott", "Andrew J. Hunt", "Jennifer R. Dodson", "Andrew F. Taylor", "Neil C. Bruce", "James H. Clark"], "doi"=>["https://dx.doi.org/10.1371/journal.pone.0087192.s001", "https://dx.doi.org/10.1371/journal.pone.0087192.s002", "https://dx.doi.org/10.1371/journal.pone.0087192.s003", "https://dx.doi.org/10.1371/journal.pone.0087192.s004", "https://dx.doi.org/10.1371/journal.pone.0087192.s005", "https://dx.doi.org/10.1371/journal.pone.0087192.s006", "https://dx.doi.org/10.1371/journal.pone.0087192.s007", "https://dx.doi.org/10.1371/journal.pone.0087192.s008", "https://dx.doi.org/10.1371/journal.pone.0087192.s009", "https://dx.doi.org/10.1371/journal.pone.0087192.s010", "https://dx.doi.org/10.1371/journal.pone.0087192.s011", "https://dx.doi.org/10.1371/journal.pone.0087192.s012", "https://dx.doi.org/10.1371/journal.pone.0087192.s013", "https://dx.doi.org/10.1371/journal.pone.0087192.s014"], "stats"=>{"downloads"=>33, "page_views"=>22, "likes"=>0}, "figshare_url"=>"https://figshare.com/articles/_Supported_Palladium_Nanoparticles_Synthesized_by_Living_Plants_as_a_Catalyst_for_Suzuki_Miyaura_Reactions_/918174", "title"=>"Supported Palladium Nanoparticles Synthesized by Living Plants as a Catalyst for Suzuki-Miyaura Reactions", "pos_in_sequence"=>0, "defined_type"=>4, "published_date"=>"2014-01-29 03:58:56"}

PMC Usage Stats | Further Information

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Relative Metric

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F1000Prime